Updated on 2025/03/21

写真a

 
NISHIKORI Hisashi
 
Organization
Research Field in Education, Law, Economics and the Humanities Area Faculty of Education Teacher Education Course (Science Education) Associate Professor
Title
Associate Professor
Degree
(2001.3 Kyushu University)

Research Interests

  • 天然有機化合物

  • 高配位ケイ素化合物

  • 有機触媒

  • 有機金属触媒

  • 不斉合成反応

Research Areas

Synthetic organic chemistry, 理科教育

Education

  • 1996.4 - 2001.3    Kyushu University

  • 1992.4 - 1996.3    Kyushu University

Research History

  • 2004.4    Kagoshima University   Associate Professor

  • 2001.11 - 2004.3    University of Tsukuba   Research Assistant

  • 2001.4 - 2001.10    University of Tsukuba

  • 1998.4 - 2001.3    Kyushu University   Special researcher of the Japan Society for the Promotion of Science

Professional Memberships

  • 2015.10    理科教育学会

  • 2015.10    有機合成化学協会

  • 2015.10    日本化学会

 

Papers

  • NISHIKORI Hisashi, YOKOYAMA Kenichi, KAMISAKI Hiroki, SAMESHIMA Keisuke, KUBO Hiroyuki, SETO Fusako and TSUCHIDA Satoshi .  Formation of the particle model of matter in elementary school (2): A dye experiment using the pericarps of dragon fruit .  Bulletin of the educational research and practice, Faculty of Education, Kagoshima University29   11 - 18   2020

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  • SOMEKAWA Kenichi, UEDA Takehiko, YOSHIDOME Toshifumi, ISHIKAWA Takeshi, NISHIKORI Hisashi .  Molecular Simulation Analysis of Novel and Chiral Diels-Alder Reactions by Basic Catalysts .  Journal of Computer Chemistry, Japan19 ( 4 ) 175 - 177   2020

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    Language：Japanese   Publisher：Society of Computer Chemistry, Japan  

    <p>The reaction process and steric situations of novel basic and chiral catalyst Diels-Alder reactions by Kagan et al. were speculated by IRC of PM7 simulation for the three molecules reactions clearly. The addition reactions of enolic dienes (<b>1</b>) with dienophiles (<b>2</b>) by amines (<b>3</b>) such as (<i>S</i>)-(+)-prolinol / (<i>R</i>)-(−)-prolinol proceeded via lower energy reaction complexes (RC) and transition states (TS) of two steps. The steric shapes by IRC (Figure 2 ∼ 6) showed the clear interactions between the reaction points, and of OH with amine moieties in the <b>1·3, 1·3·2</b> and TS complexes, to give high stereoselective adducts. IRC of some reactions also guesses right the Michael reaction selectivity. The handy PM7 simulation is recommended for usual chemical growth.</p>

    DOI： 10.2477/jccj.2021-0011

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  • Nishikori Hisashi, Seto Fusako, Tsuchida Satoshi .  Formation of the particle model of matter in elementary school(1): Dyeing experiment using pericarp of dragon fruit .    28   19 - 26   2019.3

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  • Nishikori Hisashi, Sonobata Mika, Seto fusako .  A Development study of the dyeing method using Pericarp of Dragon fruit: The Additive Effect of Onion Extract and Ascorbic Acid .    70   7 - 14   2019.3

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  • 錦織寿、川端結花、瀬口公美、瀬戸房子 .  ドラゴンフルーツを用いた絹布に染色（2）温度効果と時間変化 .  鹿児島大学教育学部研究紀要（自然科学編）66   41 - 49   2015.3

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  • 錦織寿、中馬裕香、中野聖子、瀬戸房子 .  ドラゴンフルーツの果皮を用いた絹布（シルク）の染色 .  鹿児島大学教育学部研究紀要（自然科学編）65   1 - 8   2014.3

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  • 錦織寿、田中健一、佛淵のぞみ、瀬戸房子 .  ドラゴンフルーツを用いた羊毛布の染色についての研究 .  鹿児島大学教育学部研究紀要（自然科学編）64   17 - 24   2013.3

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  • 錦織寿、石塚哲郎 .  サレン-マンガン錯体を用いたスルフィミドの速度論的分割 .  鹿児島大学教育学部研究紀要（自然科学編）63   53 - 59   2012.3

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  • Hisashi Nishikori,Tomofumi Mizuno .  A Convenient Method for Asymmetric Reduction of Acetophenone using Lithium Hydroxide .  鹿児島大学教育学部研究紀要（自然科学編）61   25 - 30   2010.3

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  • 錦織寿(NISHIKORIHisashi) .  高配位シリカートを経由するシクロヘキサン誘導体の立体選択的合成 .  鹿児島大学教育学部研究紀要（自然科学編）57   13 - 19   2005.3

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  • 錦織寿 .  Acid-Catalyzed Intramolecular Addition of a Carboxy Group to Vinylsilanes .  Organometallic Chemistry686 ( 21 ) 242 - 250   2003.12Reviewed

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  • 錦織寿(NISHIKORIHisashi) .  Optically Active Lithium-Alkoxide Catalyzed Asymmetric Reduction of Imines with Trimethoxyhydrosilane .  Synlett ( 4 ) 561 - 563   2003.4Reviewed

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  • 錦織寿 .  Lewis Acid-Catalyzed Reductive Etherification of Carbonyl Compounds with Alkoxyfydrosilanes .  Synlett ( 2 ) 313 - 315   2002.2Reviewed

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  • 錦織寿 .  Homoaldol and Aldol Reactions from Common Enolates and Oxiranes: Reaction of Reductively Generated Chromium Enolates through Cationic Rearrangement .  Chemistry Letters ( 2 ) 142 - 143   2002.2Reviewed

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  • 錦織寿 .  Intramolecular Carbostannylation via a Radical Chain Process .  Chemistry Letters ( 1 ) 32 - 33   2002.1Reviewed

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  • 錦織寿(NISHIKORIHisashi) .  Homolytic Carbostannylation of Alkenes and Alkynes with Tributylstannyl Enolates .  Organic Letters3 ( 25 ) 4055 - 4057   2001.12Reviewed

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  • 錦織寿 .  Reductive Generation of Enolates Using Chromium(III) Ate-Type Reagent as a Reductant and Reaction of the Enolates with Electrophiles .  Organometallics20 ( 24 ) 5014 - 5016   2001.11Reviewed

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  • 錦織寿 .  Acid-Catalyzed Cyclization of Vinylsilanes Bearing a Hemiacetal Group .  Chemisty Letters ( 10 ) 958 - 959   2001.10Reviewed

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  • 錦織寿 .  Lewis Acid-Catalyzed Reductive Amination of Carbonyl Compounds with Aminohydrosilanes .  Synlett ( 10 ) 1617 - 1619   2001.10Reviewed

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  • 錦織　寿 .  Study on Catalytic Asymmetric Nitrene Transfer Reactions Using Chiral(Salen)manganese(3)Complexes as Catalysts .      2001.3

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  • 錦織寿(NISHIKORIHisashi) .  Enantioselective epoxidation of conjugated trans-olefins with (salen)manganese(III) complexes as catalysts .  Synlett ( 11 ) 1557 - 1560   2000.11Reviewed

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  • 錦織寿(NISHIKORIHisashi) .  Mn-salen Catalyzed Enantioselective Sulfimidation .  Applied Catalysis A:General ( ※ ) 475 - 477   2000.4Reviewed

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  • 錦織寿(NISHIKORIHisashi) .  Mn-salen Catalyzed Nitrene Transfer Reaction: Enantioselective Sulfimidation of Alkyl Aryl Sulfides .  Tetrahedron55 ( 49 ) 13937 - 13946   1999.12Reviewed

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  • 錦織寿(NISHIKORIHisashi) .  A Short-Step Synthesis of trans-Whisky Lactone by an Asymmetric Michael Reaction .  Tetrahedron:Asymmetry9 ( 7 ) 1165 - 1170   1998.4Reviewed

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  • 錦織寿(NISHIKORIHisashi) .  Catalytic and Highly Enantioselective Aziridination of Styrene Derivatives .  Tetrahedron Letters37 ( 51 ) 9245 - 9248   1996.12Reviewed

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Presentations

  • ○錦織寿、甲斐匠一郎、瀬戸房子、土田理   小学校における粒子概念形成を目的とした植物色素を用いる染色実験  

    日本理科教育学会全国大会  2019.9  一般社団法人日本理科教育学会

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    Event date： 2019.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：静岡大学静岡キャンパス   Country：Japan  

  • 矢崎ひかる、瀬口公美、錦織寿、瀬戸房子   ドラゴンフルーツの果皮の抽出液を用いた染色法の開発  

    日本家政学会九州支部大会62回大会  （一社）日本家政学会九州支部

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    Event date： 2016.10

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：鹿児島大学  

    ドラゴンフルーツの果皮の抽出液を用いて繊維類の染色の検討を行った。検討の結果、染色時に添加が効果的な酢酸を抽出時に加えると染色効率が低下すること、また、添加剤としては液体の有機酸より固体の有機酸を用いた方が染色後の退色を抑えられることが分かった。